Novel electrospun polymer electrolytes incorporated with Keggin‐type hetero polyoxometalate fillers as solvent‐free electrolytes for lithium ion batteries

In this study, solvent‐free nanofibrous electrolytes were fabricated through an electrospinning method. Polyethylene oxide (PEO), lithium perchlorate and ethylene carbonate were used as polymer matrix, salt and plasticizer respectively in the electrolyte structures. Keggin‐type hetero polyoxometalate (Cu‐POM@Ru‐rGO, Ni‐POM@Ru‐rGO and Co‐POM@Ru‐rGO (POM, polyoxometalate; rGO, reduced graphene oxide)) nanoparticles were synthesized and inserted into the PEO‐based nanofibrous electrolytes. TEM and SEM analyses were carried out for further evaluation of the synthesized filler structures and the electrospun nanofibre morphologies. The fractions of free ions and crystalline phases of the as‐spun electrolytes were estimated by obtaining Fourier transform infrared and XRD spectra, respectively. The results showed a significant improvement in the ionic conductivity of the nanofibrous electrolytes by increasing filler concentrations. The highest ionic conductivity of 0.28 mS cm^?1 was obtained by the introduction of 0.49 wt% Co‐POM@Ru‐rGO into the electrospun electrolyte at ambient temperature. Compared with solution‐cast polymeric electrolytes, the electrospun electrolytes present superior ionic conductivity. Moreover, the cycle stability of the as‐spun electrolytes was clearly improved by the addition of fillers. Furthermore, the mechanical strength was enhanced with the insertion of 0.07 wt% fillers to the electrospun electrolytes. The results implied that the prepared nanofibres are good candidates as solvent‐free electrolytes for lithium ion batteries. © 2020 Society of Chemical Industry     

弯板式斜度机械调整卡具结构设计

机械压力机的飞轮、支撑套及圆盘类等零件在钻床、龙门铣床进行垂直、斜孔或面精密加工时,需要直立或倾斜固定于机床工作台或地平台基面,人工操作用时长,效率低,工人劳动强度大,零件倾斜角度调整定位精度较低,加工零件质量差,通过本文设计的这种弯板式斜度机械调整卡具装置可有效解决这类问题,达到零件进行垂直、斜孔或面精密加工的特殊要求。     

广西箭猪坡矿床首次发现的石英脉型锡矿体特征及 锡石微量元素地球化学意义

箭猪坡矿床是丹池成矿带南端的一个以铅锌锑为主的矿床，随着2012-2014年在箭猪坡矿床钻孔中石英脉型锡矿体的首次发现，打开了箭猪坡矿床新的找矿空间。新发现的锡矿体矿石矿物组合类型主要为锡石+闪锌矿+脆硫锑铅矿+黄铁矿+石英及锡石+脆硫锑铅矿+石英+方解石。箭猪坡矿床锡石呈自形-半自形粒状，锡石粒径多在0.1～0.2mm，少数0.02～0.05mm，分布在含硫化物的石英脉裂隙中。物相分析显示箭猪坡矿床锡主要赋存在锡石中，锡石物相占83.33%～100%。阴极发光（CL）图像显示箭猪坡矿床中的锡石经历了两期结晶作用：早期锡石（Ⅰ）和晚期锡石(Ⅱ），早期锡石CL荧光亮度较小，呈暗灰色至黑色；晚期CL荧光亮度较大，呈白色至浅灰色。锡石单矿物SnO2含量91.623%～96.288%，平均94.03%，杂质主要有Fe、W、In等，其中FeO含量0.02%～0.52%，WO3含量多在0.02～1.34%，In2O3含量在0.476%～0.954%，Sn与FeO、In2O3呈负相关，锡石中FeO、WO3、Ta2O5、Nb2O5、MnO含量指示箭猪坡锡形成于中低-中温热液环境，成矿热液来源于高度分异演化的花岗质岩浆。通过与大厂矿田西矿带上部脉状锡矿体的类比分析，具有相似的成矿条件及矿物组合，推测所揭露到的脉状锡矿（化）体相当于西矿带上部脉状锡矿（化）体，而下部的网脉状、似层状锡矿体尚未揭露到，由此预测箭猪坡矿床深部找矿空间及找矿潜力大。     

Solution combustion synthesis of cerium oxide nanoparticles as corrosion inhibitor

In this study, combustion synthesis of cerium oxide nanoparticles was reported using cerium nitrate hexahydrate as starting material as well as urea, glycine, glucose, and citric acid as fuels. The influence of fuel type on structure, microstructure, band gap, and corrosion inhibition was investigated. X-ray diffraction (XRD) patterns and scanning electron microscopy micrographs showed that CeO₂ nanoparticles with different morphologies were obtained depending on the fuel type. Microstructural changes from unreacted gel to sponge-like morphologies were resulted by varying the fuel type from urea, glycine, and glucose to citric acid. In addition to Ce–O bonds, Fourier transform infrared analysis showed carbon bonds of carbonaceous compositions from incomplete combustion which were declined during combustion reaction. Furthermore, corrosion analyses showed that samples synthesized using urea fuel released the most Ce⁺⁴ ions and could have better protection than other samples.     

面向踝部康复的广义球面并联机构型综合

针对现有踝关节康复机器人难以充分拟合踝关节复杂运动，人机相容性较差的问题，提出一系列与踝关节实际骨结构匹配程度更高的串联等效拟合模型。为满足踝关节串联等效拟合模型对康复机器人机构本体的功能需求，给出一种具有串联等效拟合模型的广义球面并联机构型综合方法。首先枚举出广义球面机构的基本构件及运动副，并依此构造出广义球面支链。继而基于螺旋理论分析单支链以及多支链组合对动平台的约束性能，给出支链的组合条件与原则，阐明不同支链在机构中作用的异同，并依此归纳出位置支链和姿态支链两类广义球面基本支链。最后基于基本支链的约束特性，根据支链组合条件，综合出一系列适用于踝关节康复机器人本体研究的广义球面并联机构，并通过螺旋理论证明其与踝关节串联等效拟合模型的自由度数及性质具有一致性，为此类康复机器人本体设计提供理论依据。     

金川集团化工厂铜冶炼烟气制酸中温位余热回收

阐述金川集团化工厂530 kt/a铜冶炼烟气制酸系统扩能改造和余热回收前存在的问题,在遵循尽可能保留现有工艺管线和保证余热高效回收的原则上对转化工艺进行改造完善,将转化流程由原设计的“3+1/Ⅳ.Ⅰ-Ⅲ.Ⅱ”四段转化改为“3+2/Ⅴ.Ⅰ-Ⅲ.Ⅱ.Ⅳ”五段转化工艺流程,研发适合冶炼烟气制酸系统的分离型热管余热回收工艺技术.生产实践证明,该工艺在确保转化热平衡的基础上提升转化率,优化系统工艺技术指标,实现回收转化中温位富余热量生产饱和蒸汽,保证制酸系统与铜冶炼系统的匹配化生产,节能减排效益可观.     

主井井塔双梁吊钩桥式起重机安装

曲江矿井主井井塔+54m平台上,需安装1台Gm=32/5T型电动双梁吊钩桥式起重机。由于吊装高度较高,空间狭小,井塔封屋顶面期间,在屋顶面预留400mm×400mm小孔,作为+46m平台的提升吊装孔;在屋顶面中间预留600mm×600mm小孔,作为+54m平台吊装孔。吊装时,先吊装左梁,再吊装右梁,小车正好落在组装好的左、右梁轨道上;然后将起重机推到机房中间位置,进行调试,完成安装。     

Ultra-smooth BaTiO3 surface morphology using chemical mechanical polishing technique for high-k metal-insulator-metal capacitors

The surface roughness of barium titanate (BTO) following its implication by aerosol deposition method (ADM), is a very important characteristic affecting its potential for use in high-k metal-insulator-metal capacitors. The ADM is the best candidate to deposit ceramic films but has two major problems: macroscopic defects and rough interface effects on the BTO surface. In this work, a chemical mechanical polishing (CMP) technique is applied to obtain an ultra-smooth BTO surface morphology by the optimization of several factors including the slurry type, the head rotational speed, and the down pressure. Statistically, we were able to achieve a root mean square (RMS) value of the BTO surface of 1.746 nm by utilizing a two-step polishing process, applied at a head rotational speed of 70 rpm under 5 kg/cm² of down pressure; this RMS value is improved at least 8 times over previous studies. This analysis is based on representative pattern images, three-dimensional images, line profiles, histograms, and power spectra of selected BTO surface areas, further verified with data from both energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy.     

Hygrothermal deformation of orthotropic nanoplates based on the state-space concept

This paper deals with the investigation of the effect of hygrothermal conditions on the bending of nanoplates using Levy type solution model employing the state-space concept. The nanoplates are assumed to be subjected to a hygrothermal environment. The two-unknown function plate theory is used to derive the governing differential equations on the basis of Eringen's nonlocal elasticity theory. The governing equations contain the small scale effect as well as hygrothermal and mechanical effects. These equations are converted into a set of first-order linear ordinary differential equations with constant coefficients. Analytical solution of bending response for nanoplates under combinations of simply supported, clamped and free boundary conditions is obtained. Comparison of the results with those being in the open literature is made. The influences played by small scale parameter, temperature rise, the degree of moisture concentration, boundary conditions, plate aspect ratio and side-to-thickness ratio are studied.     

川北某黑色页岩型铼矿工艺矿物学研究

通过矿相显微镜、扫描电镜、电子探针、X射线能谱元素面分析等多种手段综合研究了川北某黑色页岩型铼矿中铼的赋存状态。样品为黑色页岩,有机碳含量较高。粘土矿物总量为14.6%,黄铁矿含量16.2%,石英含量37.7%。样品具典型的粘土结构,矿物粒度微细。铼有两种赋存状态,一种呈类质同象形式赋存于黄铁矿内,另一种则以分散形式存在。典型黄铁矿测点Re平均含量为0.024%。黄铁矿是Re的重要载体矿物。建议通过浮选分离黄铁矿,从而实现Re的富集。